two.two]decane core and defining the geometry in the exocyclic double bond. The activation energies of formation with the vinyl-gold intermediates have been calculated and uncovered a silyl enol ether having an unprotected indole moiety as a suitable precursor for that Toste cyclization. This six-step synthesis didn't include any nonstrategic redox
two.2]decane Main and defining the geometry with the exocyclic double bond. The activation energies of development on the vinyl-gold intermediates had been calculated and discovered a silyl enol ether with an unprotected indole moiety as an appropriate precursor for that Toste cyclization. This 6-step synthesis didn't involve any nonstrategic redox
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